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Prof. em. Dr. Gerhard E. Herberich
Institut für Anorganische Chemie |
 |
1958 Vordiplom, Technische Hochschule Karlsruhe,
1960 Diplom, Universität München (E. O. Fischer),
1960-62 Dissertation, Universität München (E. O. Fischer),
1963-65 Postdoktorandenzeit: University College London (D. J. Millen),
1965-67 Physikalisches Institut der Universität Freiburg i.
Br. (H. Dreizler, H. D. Rudolph),
1967 Habilitation, Technische Hochschule München,
1971-73 Karl Winnacker-Stipendium,
1973 Chemie-Preis der Akademie der Wissenschaften zu
Göttingen,
1973-2002 Professor für Anorganische Chemie,
Technische Hochschule Aachen,
ab 2002 Professor emeritus
Borabenzene Metal Complexes
Herberich, G. E.; Ohst, H. Adv. Organomet. Chem. 1986,25,199-236.
Enantiopure Ruthenocenes Cp*Ru(1,2-C5H3R1R2)
with a Planar Chiral Cyclopentadienyl Ligand and a
Pentamethylcyclopentadienyl Spectator Ligand
Herberich, G. E.; Englert, U.; Wirth, T.; Eur.
J. Inorg. Chem. 2005, 4924–4935.
Reaction Chemistry of the Carbenoid
Butadienyl Complex Ion [CpCo(σ,η4-C4HMe4)]+
Formed by Protonation of the Cyclobutadiene Complex [CpCo(C4Me4)]
Butovskii, M. V.; Englert, U.; Herberich, G.
E.; Koelle, U.; Eur. J. Inorg. Chem. 2005, 971–980.
Bis(boryl)metallocenes, 3. Anion
Binding of 1,1'-Bis(dialkylboryl)cobaltocenium Complexes – Structures
of [Co{C5H4(BMe2)}2]PF6,
Co[C5H4(BMe2)][C5H4(BMe2Cl)],
Co[C5H4(BiPr2)]2(µ-F),
and NMe4[Co{C5H4(BiPr2F)}2]
Herberich, G. E.; Englert, U.; Fischer, A.;
Wiebelhaus, D.; Eur. J. Inorg. Chem. 2004, 4011–4020.
Tetranuclear (Borole)rhodium Clusters
with Hydrido and Methylthiolato Ligands – Structures of [{Rh(C4H4BMe)}4(µ3-H)(µ3-I)3]
and of [{Rh(C4H4BPh)}2(µ-SMe)(µ3-SMe)]2
(2 Rh-Rh)
Herberich, G. E.; Eckenrath, H. J.; Wagner,
T.; Wang, R.; Eur. J. Inorg. Chem. 2004, 1396–1401.
Borabenzene Derivatives, 40. New
Alkali Metal Boratabenzenes: Structures of K(18-crown-6)(C5H5BMe),
of the Tetrahydropyran Solvate K(3,5-Me2C5H3BNMe2)(THP)2,
and of two THF Solvates of K[3,5-Me2C5H3BN(SiMe3)2]
Zheng, X.; Herberich, G. E.; Eur. J.
Inorg. Chem. 2003, 2175–2182.
Protonation of CpCo(C4Me4):
Ring-opening with Formation of New σ,η4-Butadienyl and η5-Pentadienyl
Cobalt Complexes
Butovskii, M. V.; Englert, U.; Herberich, G.
E.; Kirchner, K.; Koelle, U.; Organometallics 2003, 22,
1989–1991.
(Tetramethylcyclobutadiene)cobalt
Complexes – Syntheses of Tris(ligand) Derivatives and Structures of [(C4Me4)Co(CO)3]BF4
and [(C4Me4)Co(NCMe)3]PF6
Butovskii, M. V.; Englert, U.; Fil'chikov, A.
A.; Herberich, G. E.; Koelle, U.; Kudinov, A. R.; Eur. J.
Inorg.Chem. 2002, 2656–2663.
Borabenzene Derivatives, 39.
Borabenzene Adducts of Ylidic Lewis Bases. Syntheses and Structures of
3,5-Me2C5H3BCH2PPh3,
3,5-Me2C5H3BCH(SiMe3)PPh3,
and C5H5BN(Ph)PPh3
Zheng, X.; Wang, B.; Herberich, G. E.; Organometallics
2002, 21, 1949–1954.
Borabenzene Derivatives, 38. Complexes
of the (Tetramethylcyclobutadiene)cobalt Fragment with Boratabenzene
Ligands and an Unprecedented Formation of a Borabenzene Complex.
Structures of (C4Me4)Co(3,5-Me2C5H3BSnMe3)
with a Sn–B bond and of the Dinuclear Complex [(C4Me4)Co(3,5-Me2C5H3B)]2O
Herberich, G. E.; Basu Baul, T. S.; Englert,
U.; Eur. J. Inorg. Chem. 2002, 43–48.
Borabenzene Derivatives, 37.
1-Aminoboratabenzene Complexes of Scandium Group Metals
Wang, B.; Zheng, X.; Herberich, G. E.; Eur.
J. Inorg. Chem. 2002, 31–41.
Borabenzene Derivatives, 36. Bent
Metallocenes of Germanium, Tin, and Lead with Aminoboratabenzene
Ligands – Crystal Structures of E[3,5-Me2C5H3BN(SiMe3)2]2
(E = Ge, Sn, and Pb)
Zheng, X.; Herberich, G. E.; Eur. J.
Inorg. Chem. 2001, 3013–3019.
Borabenzene Derivatives. 35. Lithium (S)-1-[2'-(Methoxymethyl)pyrrolidin-1'-yl]-3,5-dimethylboratabenzene.
An Enantiopure Lithium Salt Possessing a Novel Polymeric Structure
Zheng, X.; Herberich, G. E.; Organometallics
2001, 20, 3097–3100.
Borabenzene Derivatives. 34. Three
Conformational Polymorphs of
Di-µ-chlorotetrakis(1-methylboratabenzene)diyttrium: Synthesis,
X-ray
Structures, Quantum Chemical Calculations, and Lattice Energy
Minimizations
Zheng, X.; Wang, B.; Englert, U.; Herberich,
G. E.; Inorg. Chem. 2001, 40, 3117–3123.
Heterometallic complexes and clusters
with 2-boratanaphthalene ligands
Braunstein, P.; Cura, E.; Herberich, G. E.; J.
Chem. Soc., Dalton Trans. 2001, 1754–1760.
A quest for triple-decker complexes
with a bridging phospholyl ligand. Syntheses of [(µ,η5:η5-C4Me4P)(FeCp*)(RhCp*)](BF4)2
and [(µ,η5:η5-C4Me4P)(FeCp*)(IrCp*)](BF4)2,
and structures of [Cp*Fe(µ,η1:η5-C4Me4P)Ir(NCMe)2Cp*)](CF3SO3)2(Me2CO)
and [(C5Me4CH2C6H11)Fe(µ,η1:η5-C4Me4P)Rh(O3CF3)2Cp*
Herberich, G. E.; Ganter, B.; Inorg.
Chem. Commun. 2001, 4, 100–103.
Borabenzene Derivatives. 32. Syntheses
and Structures of Mg(C5H5BMe2)2,
Mg(3,5-MeC5H3BNMe2)2, the
2,2'-Bipyridine Adduct Mg(C5H5BMe)2(bipy),
and the N-Bonded Aminoboratabenzene Species Mg(3,5-Me2C5H3BNMe2)2(THF)2
Zheng, X.; Englert, U.; Herberich, G. E.;
Rosenplänter, J.; Inorg. Chem. 2000, 39,
5579–5585.
Borabenzene Derivatives. 33.
3,5-Dimethylborabenzene-1,3,4,5-Tetramethylimidazol-2-ylidene: The
First Carbene Adduct of a Borabenzene
Zheng, X.; Herberich, G. E.; Organometallics
2000, 19, 3751–3753.
Borabenzene Derivatives. 31.
Enantiomerically Pure Complexes of Manganese, Iron, and Zirconium with
Pinene-fused Boratabenzene Ligands – Structures of exo-FeCp*(C13H17BNMe2)
and exo,exo-ZrCl2(C13H17BNMe2)2
Herberich, G. E.; Englert, U.; Ganter, B.;
Pons, M.; Eur. J. Inorg. Chem. 2000, 979–986.
Borabenzene Derivatives. 29. Synthesis
and Structural Diversity of Bis(boratabenzene)scandium Complexes.
Structures of [ScCl(C5H5BMe)2]2,
[ScCl(3,5-Me2C5H3BNMe2)2]2,
and ScCl[3,5-Me2C5H3BN(SiMe3)2]2
Herberich, G. E.; Englert, U.; Fischer, A.;
Ni, J.; Schmitz, A.; Organometallics 1999, 18,
5496–5501.
Borabenzene Derivatives. 30.
Bis(1-methylboratabenzene) Compounds of Germanium, Tin, and Lead. First
Structural Characterization of Facial Bonding of a Boratabenzene to a
p-Element, and the Structures of Pb(C5H5BMe)2
and its 2,2'-Bipyridine Adduct
Herberich, G. E.; Zheng, X.; Rosenplänter,
J.; Englert, U.; Organometallics 1999, 18,
4747–4752.
A new synthetic route to
2-boratanaphthalenes
Herberich, G. E.; Cura, E.; Ni, J.; Inorg.
Chem. Commun. 1999, 2, 503–506.
Heterometallic Complexes with Borole
Ligands
Braunstein, P.; Englert, U.; Herberich, G.
E.; Neuschütz, M.; Schmidt, M. U.; J. Chem. Soc., Dalton Trans.
1999, 2807–2812.
Borabenzene Derivatives. 28.
Pinene-Fused Dihydroborinines, Boratabenzenes, and a
Borabenzene-Pyridine Adduct
Herberich, G. E.; Englert, U.; Ganter, B.;
Pons, M.; Wang, R.; Organometallics 1999, 18,
3406–3413.
Tribenzylidenemethane complexes of
ruthenium. Synthesis and effects of the diastereo-isomerism on the
crystal packing
Herberich, G. E.; Spaniol, T. P.; J.
Organomet. Chem. 1999, 582, 338–344.
Cyano-bridged Fe-CN-Pt-NC-Fe chain
complexes: structural and spectroscopic characterization of four
isomers of [{η5-(1-phenylborole)Fe(CO)2(µ-CN)}2Pt(PEt3)2]
Braunstein, P.; Herberich, G. E.;
Neuschütz,
M.; Schmidt, M. U.; J. Organomet. Chem. 1999, 580,66–71.
Synthesis of borylindenides. Complexes
with iron and rhenium moieties
Barday, E.; Frange, B.; Hanquet, B.;
Herberich,G. E.; J. Organomet. Chem. 1999, 572,
225–232.
Triple-Decker Complexes. 14. A Model
for the End-for-End Disordered Cationic Triple-Decker Complex
[Cp*Ru(µ-η5:η5-C5Me4P)FeCp*]+
Herberich, G. E.; Ganter, B.; Englert, U.; Structural
Chemistry 1998, 9, 359–363.
Cyclopentadienyl(pentamethylcyclopentadienyl)iron
Derivatives. A New and Highly Selective Synthesis
Herberich, G. E.; Gaffke, A.; Eckenrath, H.
J.; Organometallics 1998, 17, 5931–5932.
Bis(boryl)metallocenes. 2. Synthesis of
1,1'-Bis(boryl)cobaltocenium Complexes
Herberich, G. E.; Englert, U.; Fischer, A.;
Wiebelhaus, D.; Organometallics 1998, 17,
4769–4775.
Synthesis of borylindenides; structure
of [Li(N,N',N''-Me3-1,3,5-C3H6N3)][1-C9H6{B(NMe2)2}]
Herberich, G. E.; Barday, E.; Fischer, A.; J.
Organomet. Chem. 1998, 567, 127–131.
Heterometallic Borole Complexes of Iron
and Gold
Braunstein, P.; Herberich, G. E.;
Neuschütz,
M.; Schmidt, M. U.; Englert, U.; Lecante, P.; Mosset, A.; Organometallics
1998, 17, 2177–2182.
Borabenzene Derivatives. 27. From
(-)-α-Pinene to the First Chiral Boratabenzene Salt
Herberich, G. E.; Ganter, B.; Pons, M.; Organometallics
1998, 17, 1254–1256.
Borole Derivatives. 24. Synthesis of
Cationic (Arene)(phenylborole)rhodium Complexes. Structures of the
Trinuclear Complex (η5-C4H4BPh)Rh(µ3-I)3Rh(µ,η5:η6-C4H4BPh)Rh(η5-C4H4BMe)·CH2Cl2
and of the Polymeric catena-(µ,η5:η6-1-phenylborole)rhodium
Tetrafluoroborate
Herberich, G. E.; Eckenrath, H. J.; Englert,
U.; Organometallics 1998, 17, 519–523.
Borole Derivatives. 23. Reversible
Carbonylation and Lewis Base Degradation of the Heterocubane [Rh(µ3-I)(C4H4BPh)]4
and of the Bis(borole) Complex RhI(C4H4BPh)2,
and Synthesis and Structure of a Dinuclear Complex Cp*Rh(µ-I)3Rh(C4H4BPh)
Herberich, G. E.; Eckenrath, H. J.; Englert,
U.; Organometallics1997,16,4800–4806.
Borole Derivatives. 22. Iodine
Degradation of the Triple-Decker Complexes (µ-C4H4BR)[Rh(C4H4BR)]2(R
= Ph, Me): Synthesis and Structural Characterization of
Heterocubanes[Rh(µ3-I)(C4H4BR)]4
and of Bis(borole)rhodium Complexes RhI(C4H4BR)2
Herberich, G. E.; Eckenrath, H. J.; Englert,
U.; Organometallics 1997, 16, 4292–4298.
Borabenzene Derivatives. 26. Syntheses
of 1-Methylboratabenzene Complexes of Titanium, Zirconium, and Hafnium.
Structures of TiCl3(C5H5BMe), TiCl2Cp(C5H5BMe),
ZrCl2Cp*(C5H5BMe), and ZrCl2(C5H5BMe)2
Herberich, G. E.; Englert, U.; Schmitz, A.; Organometallics
1997, 16, 3751–3757.
Derivative des Borabenzols. 25.
Methylbis(1-methylboratabenzol)indium: Synthese und Struktur. Ein
Beispiel für die Variabilität weicher molekularer
Strukturparameter
unter dem Einfluß der Kristallgitterkräfte
Herberich, G. E.; Englert, U.;
Rosenplänter,
J.; Z. Anorg. Allg. Chem. 1997, 623, 1098–1102.
Boratabenzene Chemistry Revisited
Herberich, G. E. In Advances in Boron
Chemistry; Siebert, W., Ed.; The Royal Society of Chemistry,
Cambridge U.K., Special Publication No. 201, 1997,
211–223.
Borabenzene Derivatives. 24. From
Lithium 1-Methylboratabenzene to 2-Mono- and 2,2-Disubstituted
1-Methyl-1,2-dihydroborinines with Me3Si,Me3Ge, Me3Sn,
and Me3Pb Substituents. Degenerate Sigmatropic
Rearrangements with Exceptionally Low Barriers, and Structure of 2-(Me3Sn)C5H5BMe
Herberich, G. E.; Rosenplänter, J.;
Schmidt,
B.; Englert, U.; Organometallics 1997, 16,
926–931.
Triple-Decker Complexes. 13. Synthesis
of the First Triple-Decker Complexes with a Bridging Phospholyl Ligand.
Structures of the Triple-Decker Complex [(µ-C4Me4P){Fe(C5Me4CH2C6H11)}(RuCp*)]CF3SO3
and of the Related Sandwich Complex Fe(C4Me4P)(C5Me4CH2C6H11)
Herberich, G. E.; Ganter, B.; Organometallics
1997, 16, 522–524.
New preparative access to and the
crystal and molecular structure of cis-PtCl2(CO)2
Bagnoli, F.; Belli Dell'Amico, D.;
Calderazzo, F.; Englert, U.; Marchetti, F.; Herberich, G. E.;
Pasqualetti, N.; Ramello, S.; J. Chem. Soc., Dalton Trans. 1996,
4317–4318.
Triple-Decker Complexes. 12.
Triple-Decker Complexes with Bridging Boratabenzene Ligands. Syntheses,
Structures of [(µ-C5H5BMe)(FeCp*)2]PF6
and of [(µ-C5H5BMe){Rh(COD)}2]CF3SO3,
and Boratabenzene Transfer Reactions
Herberich, G. E.; Englert, U.; Ganter, B.;
Lamertz, C.; Organometallics 1996, 15,
5236–5241.
Bis(boryl)metallocenes. 1.
1,1'-Bis(diisopropylboryl)cobaltocenium Cation: A Novel Anion-Binding
Ligand
Herberich, G. E.; Fischer, A.; Wiebelhaus,
D.; Organometallics 1996, 15, 3106–3108.
Borabenzene Derivatives. 23. New
Synthetic Entry into Borabenzene Chemistry via Doubly Kaliated
Pentadienes: Synthesis of
1-(Dimethylamino)-3-methylene-1,2,3,6-tetrahydroborinines and of
Lithium 1-(Dimethylamino)boratabenzene Derivatives
Herberich, G. E.; Englert, U.; Schmidt, M.
U.; Standt, R.; Organometallics 1996, 15,
2707–2712.
9-Borabarbaralanes
Herberich, G. E.; Marx, H.-W.; Moss, S.;
Schleyer, P. v. R.; Wagner,T.; Chem. Eur. J. 1996, 2,
458–461.
Borylcyclopentadienides
Herberich, G. E.; Fischer, A.; Organometallics
1996, 15, 58–67.
Triple-Decker Complexes. XI.
Triple-Decker Complexes as Intermediates in Cyclopentadienyl Transfer
Reactions: Stereospecific Transfer of Isodicyclopentadienyl Ligands
from Ruthenium to Rhodium
Herberich, G. E.; Jansen, U. J.; Organometallics
1995, 14, 834–841.
Borabenzene Derivatives, XXII.
Synthesis of Boratabenzene Salts from 2,4-Pentadienylboranes. Structure
of [NMe3Ph][C5H5BMe]
Herberich, G. E.; Schmidt, B.; Englert, U.; Organometallics
1995, 14, 471–480.
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